Production of Butene-1 from Ethylene

Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst

Current heterogeneous catalysts lack the fine steric and electronic tuning required for catalyzing the selective dimerization of ethylene to 1-butene, which remains one of the largest industrial processes still catalyzed by homogeneous catalysts. Here, we report that a metal-organic framework catalyzes ethylene dimerization with a combination of activity and selectivity for 1-butene that is pre...

Production of 1-Butene via Selective Ethylene Dimerization by Addition of Bromoethane as a New Promoter to Titanium-Based Catalyst in the Presence of Tetrahydropyran Modifier and Triethylaluminum Co-Catalyst

An investigation on non-isothermal crystallization behavior and morphology of polyamide 6/ poly(ethylene-co-1-butene)-graft-maleic anhydride/organoclay nanocomposites

Nanocomposites based on polyamide 6 (PA6) and poly(ethylene-co-1-butene)-graft-maleic anhydride (EB-g- MAH) blends have been prepared via melt mixing. The effect of blend ratio and organoclay concentration on the crystallization and melting behavior of specimens were studied. Three types of commercial organo-modified clay (Cloisite 30B, Cloisite 15A and Cloisite 20A) were employed to assess the...

Biomediated Production of Ethylene Glycol

Methods to break down hemicellulose contained in biomass into simple 5-carbon sugars are well documented. This invention comprises an enzymatic reaction scheme to convert the simple sugars (e.g., xylose, arabinose, etc.) to ethylene glycol in three stages. First, the sugar is cleaved enzymatically into glycolaldehyde and dihydroxyacetone phosphate. Second, dihydroxyacetone -a byproduct from the...

Stress induced ethylene production, ethylene binding, and the response to the ethylene action inhibitor 1-MCP in miniature roses

In an interior environment, the display life of miniature potted roses (Rosa hybrida L.) `Bronze' was 7 days, while that of `Vanilla' was 23 days. Although there was a substantial difference in ethylene production between flowers from two cultivars, there was no difference in binding site activity (kd ˆ 0.14 nl lÿ1). Pre-treatment with the ethylene action inhibitor 1-methylcyclopropene (1-MCP) ...